S-matrix
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In physics, the scattering matrix (S-matrix) relates the initial state and the final state for an interaction of particles. It is used in quantum mechanics, scattering theory and quantum field theory.
More formally, the S-matrix is defined as the unitary matrix connecting asymptotic particle states in the Hilbert space of physical states (scattering channels). While the S-matrix may be defined for any background (spacetime) that is asymptotically solvable and has no horizons, it has a simple form in the case of the Minkowski space. In this special case, the Hilbert space is a space of irreducible unitary representations of the inhomogeneous Lorentz group; the S-matrix is the evolution operator between time equal to minus infinity, and time equal to plus infinity. It can be shown that if a quantum field theory in Minkowski space has a mass gap, the state in the asymptotic past and in the asymptotic future are both described by Fock spaces.
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[edit] Explanation
[edit] Use of S-matrices
The S-matrix is closely related to the transition probability amplitude in quantum mechanics and to cross sections of various interactions; the elements (individual numerical entries) in the S-matrix are known as scattering amplitudes. Poles of the S-matrix in the complex-energy plane are identified with bound states, virtual states or resonances. Branch cuts of the S-matrix in the complex-energy plane are associated to the opening of a scattering channel.
In the Hamiltonian approach to quantum field theory, the S-matrix may be calculated as a time-ordered exponential of the integrated Hamiltonian in the Dirac picture; it may be also expressed using Feynman's path integrals. In both cases, the perturbative calculation of the S-matrix leads to Feynman diagrams.
In scattering theory, the S-matrix is an operator mapping free particle in-states to free particle out-states (scattering channels) in the Heisenberg picture. This is very useful because we cannot describe exactly the interaction (at least, the most interesting ones).
[edit] Mathematical definition
In Dirac notation, we define
as the vacuum quantum state. If
is a creation operator, its hermitian conjugate (destruction or annihilation operator) acts on the vacuum as follows:
Now, we define two kinds of creation/destruction operators, acting on different Hilbert spaces (IN space i, OUT space f),
and
.
So now
It is possible to prove that
and
are both invariant under translation and that the states
and
are eigenstates of the momentum operator
.
In the Heisenberg picture the states are time-independent, so we can expand initial states on a basis of final states (or vice versa) as follows:
Where
is the probability that the interaction transforms
into 
According to Wigner's theorem, S must be a unitary operator such that
. Moreover, S leaves the vacuum state invariant and transforms IN-space fields in OUT-space fields:
- φf = S − 1φfS
If S describes an interaction correctly, these properties must be also true:
If the system is made up with a single particle in momentum eigenstate
, then 
The S-matrix element must be nonzero if and only if momentum is conserved.
[edit] S-matrix and evolution operator U
Therefore
where
because
Substituting the explicit expression for U we obtain:
By inspection it can be seen that this formula is not explicitly covariant.
[edit] See also
[edit] Bibliography
Barut (1967). The Theory of the Scattering Matrix.
Tony Philips (11 2001). Finite-dimensional Feynman Diagrams. What's New In Math. American Mathematical Society. Retrieved on 2007-10-23.











