Vanadium(IV) fluoride
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| Vanadium(IV) fluoride | |
|---|---|
| Image:Vanadium(IV) fluoride.jpg | |
| Other names | vanadium tetrafluoride |
| Identifiers | |
| CAS number | [10049-16-8] |
| Properties | |
| Molecular formula | VF4 |
| Molar mass | 126.9351 g/mol |
| Appearance | lime green powder |
| Density | 2.975 g/cm³, solid |
| Melting point |
325 °C |
| Boiling point |
decomposes |
| Solubility in water | decomposes |
| Hazards | |
| EU classification | not listed |
| Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) Infobox disclaimer and references |
|
Vanadium(IV) fluoride (VF4) is a chemical compound of vanadium and fluorine. VF4 can be prepared by reacting VCl4 with HF in CCl3F at 25 °C. VF4 decomposes at approximately 150°C to form VF3.
The structure of VF4 is related to that of SnF4 and has corner sharing VF6 octahedra. It is paramagnetic.[1]
[edit] General references
- WebElements
- Cotton, F. Albert; Wilkinson, Geoffrey; Murillo, Carlos A.; Bochmann, Manfred (1999). Advanced Inorganic Chemistry (6th Edn.) New York:Wiley-Interscience. ISBN 0-471-19957-5.
[edit] References
- ^ Vanadium Tetrafluoride, Becker S., Muller B. G., Angew. Chem. Intnl. Ed. Engl. 29 (1990) No. 4 406

