Solanocapsine

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Solanocapsine
Other names (2S,4aS,4bS,6aS,6bR,7S,7aR,10R,11aS,12aR,13aS,13bR,15aS)-
2-Aminodocosahydro-4a,6a,7,10-tetramethylnaphth[2,1:4',5']indeno
[1',2':5,6]pyrano[3,2-b]pyridin-11a(1H)-ol;

3β-Amino-22,26-epimino-16α,23-epoxy-5α,22αH,25βH-cholestan-23β-ol; (3β,5α,16α,22α,23β,25β)-3-Amino-16,23-epoxy-16,28-secosolanidan-23-ol
Identifiers
CAS number [639-86-1]
SMILES N[C@H]1CC[C@@]2(C)[C@](CC[C@]3([H])[C@]2([H])CC[C@@]4(C)[C@@]3([H])
C[C@]5([H])[C@]4([H])[C@H](C)C6[C@@](C[C@@H](C)CN6)(O)O5)([H])C1
Properties
Molecular formula C27H46N2O2
Molar mass 430.666
Appearance long flat colorless prisms (ethanol-H2O)[1]
Melting point

222 oC[1], 216-217oC[2]
Except where noted otherwise, data are given for
materials in their standard state
(at 25 °C, 100 kPa)
Infobox disclaimer and references

Solanocapsine is a toxic steroidal alkaloid from Solanum pseudocapsicum (Jerusalem cherry).

[edit] References

  1. ^ a b Barger, L. G.; Fraenkel-Conrat, H. L. Journal of the Chemical Society, 1936, 1537-42.
  2. ^ Schlittler, E.; Uehlinger, H. Helvetica Chimica Acta, 1952, 35, 2034-44.