Lithium sulfide
From Wikipedia, the free encyclopedia
| Lithium Sulfide | |
|---|---|
| IUPAC name | Dilithium sulfanide |
| Other names | Dilithium sulfide |
| Identifiers | |
| CAS number | [12136-58-2] |
| PubChem | |
| EINECS number | |
| Properties | |
| Molecular formula | Li2S |
| Molar mass | 45.947(9) gmol-1 |
| Appearance | white solid |
| Density | 1.66 gcm-3, 1.64 gcm-3 |
| Melting point |
938 °C (1211 K) |
| Boiling point |
1372 °C (1645 K) |
| Related compounds | |
| Other anions | Lithium oxide |
| Other cations | Sodium sulfide Potassium sulfide |
| Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) Infobox disclaimer and references |
|
Lithium sulfide is the inorganic compound with the formula Li2S. This solid, which crystallises in the antifluorite motif, is described as the salt (Li+)2S2-. In 2005, lithium sulfide found use in batteries, the system being related to the sodium-sulfur battery.
Lithium sulfide is prepared by treating lithium with sulfur. This reaction is conveniently conducted in anhydrous ammonia.[1]
- 16Li + S8 → 8Li2S
[edit] References
- ^ Rankin, D. W. "Digermanyl Sulfide" Inorganic Syntheses 1974, XV, pages 182-184.
- ^ Webelements – Lithium Sulfide. Retrieved on 2005-09-16.
- ^ An article on lithium sulfide in batteries from Electronics Weekly. Retrieved on 2005-09-16.

