Disilane

From Wikipedia, the free encyclopedia

Disaline
Disilane
Disilane
IUPAC name disilicon hexahydride
Other names disilane
silicon hydride
silicon(III) hydride
Identifiers
CAS number [1590-87-0]
Properties
Molecular formula Si2H6
Molar mass 62.219 g/mol
Appearance Colourless,
odourless flammable gas
Density 2.7 kg/m3
Melting point

-132°C (141 K)

Boiling point

-14°C (259 K)

Solubility in water Insoluble
Structure
Molecular shape Tetrahedral
Dipole moment 0 D
Hazards
Main hazards Flammable, Toxic, can cause burns when in contact with skin,

and can cause respiratory problems

Flash point (Very flammable)
Related compounds
Related covalent hydrides ethane
diborane
Except where noted otherwise, data are given for
materials in their standard state
(at 25 °C, 100 kPa)

Infobox disclaimer and references

Disilane is a poisonous silicon-hydrogen compound, existing as a gas at room temperature and pressure. It is analogous to ethane, though much more reactive than ethane, due to the larger size of the silicon atom and the weaker Si-Si bonding. Traces are formed during the hydrolysis of magnesium silicide, which produces mainly silane, siloxanes, and polysiloxanes.[1] The presence of traces of disilane is responsible for the spontaneous flammability of silane produced this way, as is diphosphine for phosphine.

[edit] Uses

Disilane is occasionally used as a source of hydrogen during reactions.[2] It is also utilized in the production of silicon wafers[3].

[edit] References

  1. ^ Cost-Effective Method for the Synthesis of Polysilanes
  2. ^ Disilane
  3. ^ Disilane
Languages