Bromodifluoroacetylchloride
From Wikipedia, the free encyclopedia
| Please help improve this article or section by expanding it. Further information might be found on the talk page or at requests for expansion. (February 2007) |
| This article or section is in need of attention from an expert on the subject. WikiProject Chemistry or the Chemistry Portal may be able to help recruit one. |
| Bromodifluoroacetylchloride | |
|---|---|
| IUPAC name | 2-bromo-2,2-difluoro-ethanoyl chloride |
| Identifiers | |
| CAS number | [3832-48-2] |
| PubChem | |
| SMILES | C(=O)(C(F)(F)Br)Cl |
| Properties | |
| Molecular formula | C2BrCl2O |
| Molar mass | 193.37 g mol-1 |
| Boiling point |
50 |
| Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) Infobox disclaimer and references |
|
Bromodifluoroacetylchloride is a chemical compound with the formula BrCF2COCl. It has been used as a starting material for the synthesis of (biologically active) α,α-difluoro-γ-lactams.[1]
[edit] References
- ^ Hideo Nagashima, Yoshimi Isono, and Sho-ichi Iwamatsu, "Copper-Catalyzed Cyclization of N-Allylhalodifluoroacetamides: An Efficient Synthesis of α,α-difluoro-γ-lactams", J. Org. Chem., 66 (1), 315 -319, 2001. S0022-3263(00)01187-7 doi
- ChemicalDetail: Details for an Individual Chemical: 2-bromo-2,2-difluoro-acetyl chloride. ChemDB: The UC Irvine ChemDB. Retrieved on 2007-01-31.

